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JUSTC-2024-0059 Supporting_Information Download(6776KB)JUSTC-2024-0059 Supporting_Information
Figures of the Article
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Selected α-diimine nickel complexes.
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Synthesis of α-diimine ligands L1–L3 and nickel catalysts Ni1–Ni3.
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(a) Molecular structures of Ni2 (CCDC number 2348877 ).The selected bond lengths (Å) and angles (°) were as follows: Ni1–N1 2.025(2), Ni1–N2 2.025(2), Ni1–Br12.3315 (4), Ni1–Br22.3315 (4), N1–Ni1–N2 82.40(14), Br2–Ni1–Br1 115.38(3). (b) Molecular structures of Ni3 (CCDC number2348878 ).The selected bond lengths (Å) and angles (°) were as follows: Ni1–N12.034(2), Ni1–N2 2.209(2), Ni1–Br12.4368 (5), Ni1–Br22.3539 (5), N1–Ni1–N2 80.15(9), Br2–Ni1–Br1 130.943(18). -
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(a) Stress‒strain curves of the polymer samples obtained from Ni1 at 50 °C, 80 °C and 100 °C. (b) Stress‒strain curves of the polymer samples obtained from Ni1–Ni3 at 80 °C. (c) Fracture stress and Young’s modulus of the polymer samples generated from Ni1–Ni3 at 80 °C. (d) Strain recovery curve of the polymer sample from Table 1, entry 3.
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