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CN 34-1054/N

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Ir-ReOx/SiO2 combined with HZSM-5 as catalyst to convert biomass into C5/C6 alkane

  • 1.

    Department of Thermal Science and Energy Engineering,University of Science and Technology of China,Hefei 230027,China

  • 2.

    Department of Chemistry,University of Science and Technology of China,Hefei 230026,China

Cite this:
https://doi.org/10.3969/j.issn.0253-2778.2017.05.002
  • Received Date: 16 March 2016
  • Rev Recd Date: 12 May 2016
  • Publish Date: 31 May 2017
    Abstract

  • Abstract

    Ir-ReOx/SiO2 combined with HZSM-5 was used as catalyst for biogasoline production in the biphasic system. The effects of various parameters such as reaction time, temperature and hydrogen pressure on the yield of biogasoline were investigated. The experiment results show that, when using biomass as substrate, a maximum C5/C6 alkane yield is obtained under the optimal conditions with the reaction temperature being 170 ℃ and hydrogen pressure 7 MPa. In addition, It is found that dehydration reaction is the control step in the experiment. Compared with other catalysts, HZSM-5 has suitable Lewis acid and Bronsted acid, and it has a channel architecture which can increase substrate concentration and thus shows better catalytic activity.

    Abstract

    Ir-ReOx/SiO2 combined with HZSM-5 was used as catalyst for biogasoline production in the biphasic system. The effects of various parameters such as reaction time, temperature and hydrogen pressure on the yield of biogasoline were investigated. The experiment results show that, when using biomass as substrate, a maximum C5/C6 alkane yield is obtained under the optimal conditions with the reaction temperature being 170 ℃ and hydrogen pressure 7 MPa. In addition, It is found that dehydration reaction is the control step in the experiment. Compared with other catalysts, HZSM-5 has suitable Lewis acid and Bronsted acid, and it has a channel architecture which can increase substrate concentration and thus shows better catalytic activity.
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    • References(18)
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    CHEN K, TAMURA M, YUAN Z, et al. One-pot conversion of sugar and sugar polyols to n-alkanes without C-C dissociation over the Ir-ReOx/SiO2 catalyst combined with HZSM-5[J]. ChemSusChem，2013，6(4)：613-621.
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    AHMED I, KHAN N Ａ, MISHRA D K, et al. Liquid-phase dehydration of sorbitol to isosorbide using sulfated titania as a solid acid catalyst[J]. Chemical Engineering Science，2013， 93(1)： 91-95.
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    YEPEZ A, PINEDA A, GARCIA A, et al. Chemical transformations of glucose to value added products using Cu-based catalytic systems[J]. Physical Chemistry Chemical Physics，2013，15(29)：12165-12172.
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    XU Zhiping，LI Wenzhi，DU Zhijie，et al. Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in γ-valerolactone [J]. Bioresource Technology，2015，198:764-771.
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    [1]
    YUE Zhengbo，MA Ding，PENG Shuchuan，et al. Integrated utilization of algal biomass and corn stover for biofuel production[J]. Fuel，2016，168：1-6.
    [2]
    HOPPE F，BURKE U，THEWES M，et al. Tailor-made fuels from biomass: Potentials of 2-butanone and 2-methylfuran in direct injection spark ignition engines[J].Fuel，2016，167：106-117.
    [3]
    SERRANO-RUIZ JC，DUMESIC JA. Catalytic routes for the conversion of biomass into liquid hydrocarbon transportation fuels[J]. Energy & Environmental Science，2011，4(1)：83-99.
    [4]
    CHANDRA R P, BURA R，MABEE W E，et al. Substrate pretreatment: The key to effective enzymatic hydrolysis of lignocellulosics? [J]. Biofuels，2007， 108：67-93.
    [5]
    WEST R M, TUCKER M H，BRADEN D J，et al. Production of alkanes from biomass derived carbohydrates on bi-functional catalysts employing niobiumbased supports[J]. Catalysis Communications,2009，10(13)：1743-1746.
    [6]
    DORA S, BHASKAR T, SINGH R, et al. Effective catalytic conversion of cellulose into high yields of methyl glucosides over sulfonated carbon based catalyst[J]. Bioresource Technology，2012，120：318-321.
    [7]
    BARRETT C J, CHHEDA J N, HUBER G W, et al. Single-reactor process for sequential aldol-condensation and hydrogenation of biomass-derived compounds in water[J]. Applied Catalysis B: Environmental，2006，66(1/2)：111-118.
    [8]
    LI N, HUBER G W. Aqueous-phase hydrodeoxygenation of sorbitol with Pt/SiO2-Al2O3: Identification of reaction intermediates[J]. Journal of Catalysis，2010，270(1)：48-59.
    [9]
    周华，王铁军，张兴华，等. Pt/HZSM-5水相重整山梨醇合成生物汽油的研究 [J]. 太阳能学报，2010，31（9）：1097-1100.
    ZHOU Hua，WANG Tiejun，ZHANG Xinghua，et al. Study on aqueous-phase reforming sorbitol to bio-basoline over Pt/HZSM-5[J]. Acta Energlae Solaris Sinica，2010，31(9)：1097-1100.
    [10]
    陈泽智，陈迁，杨金兰，等. 以蔗渣为原料制备生物汽油中间体 5-氯甲基糠醛 [J]. 农业工程学报，2012，28（24）：214-219.
    CHEN Zezhi，CHEN Qian，YANG Jinlan，et al. Preparation of 5-chloromethylfurfural as potential intermediate for biofuels using bagasses as raw material [J]. Transactions of the Chinese Society of Agricultural Engineerin，2012，28（24）：214-219.
    [11]
    ZHANG Qing, WANG Tiejun , XU Ying, et al. Production of liquid alkanes by controlling reactivity of sorbitol hydrogenation with a Ni/HZSM-5 catalyst in water[J]. Energy Conversion and Management，2014，77(1)：262-268.
    [12]
    BEECK B O D, DUSSELIER M, GEBOERS J, et al. Direct catalytic conversion of cellulose to liquid straight-chain alkanes[J]. Energy & Environmental Science，2015， 8：230- 240.
    [13]
    CHEN K, TAMURA M, YUAN Z, et al. One-pot conversion of sugar and sugar polyols to n-alkanes without C-C dissociation over the Ir-ReOx/SiO2 catalyst combined with HZSM-5[J]. ChemSusChem，2013，6(4)：613-621.
    [14]
    SLUITER A, HAMES B, HYMAN D, et al. 2008. Determination of total solids in biomass and total dissolved solids in liquid process samples[R]. National Renewable Energy Laboratory,2008: NREL/TP-510-42621.
    [15]
    孙多志，黄清发，虞爱娜，等. 秸秆稀酸水解液的气相色谱／质谱法研究 [J]. 分析科学学报，2008，24（4）：409-413.
    SUN Duozhi，HUANG Qingfa，YU Aina，et al. Studies on the dilute acid hydrolysate of corn stover with gas chromatography:Mass spectrometry[J]. Journal of Analytical Science，2008，24(4)：409-413.
    [16]
    AHMED I, KHAN N Ａ, MISHRA D K, et al. Liquid-phase dehydration of sorbitol to isosorbide using sulfated titania as a solid acid catalyst[J]. Chemical Engineering Science，2013， 93(1)： 91-95.
    [17]
    YEPEZ A, PINEDA A, GARCIA A, et al. Chemical transformations of glucose to value added products using Cu-based catalytic systems[J]. Physical Chemistry Chemical Physics，2013，15(29)：12165-12172.
    [18]
    XU Zhiping，LI Wenzhi，DU Zhijie，et al. Conversion of corn stalk into furfural using a novel heterogeneous strong acid catalyst in γ-valerolactone [J]. Bioresource Technology，2015，198:764-771.
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